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91.
In Portugal, due to the combination of climatological and ecological factors, large wildfires are a constant threat and due to their economic impact, a big policy issue. In order to organize efficient fire fighting capacity and resource management, correct quantification of the risk of large wildfires are needed. In this paper, we quantify the regional risk of large wildfire sizes, by fitting a Generalized Pareto distribution to excesses over a suitably chosen high threshold. Spatio-temporal variations are introduced into the model through model parameters with suitably chosen link functions. The inference on these models are carried using Bayesian Hierarchical Models and Markov chain Monte Carlo methods.  相似文献   
92.
This work investigates the capability of an oceanic numerical model dynamic and thermodynamically coupled to a three-dimensional mesoscale atmospheric numerical model to simulate the basic features of the air–sea interaction in the coastal upwelling area of Cabo Frio (RJ, Brazil). The upwelling/downwelling regime is an important feature in the oceanic circulation of Cabo Frio and determines the sustainability of local ecosystems. This regime is predominantly driven by the atmospheric circulation and is well documented, being suitable to be used as test reference for atmospheric and oceanic coupled and uncoupled models. The oceanic boundary conditions, coastline shape and coupling effect have been tested. The uncoupled oceanic model forced by a NE (SW) wind field generates a realistic upwelling (downwelling) phenomenon regardless of the proximity of the lateral boundary and how realistic is the shape of the coastline. The atmospheric-oceanic coupled model generates an upwelling location and intensity similar to the uncoupled simulation, but the upwelling is gradually enhanced by the sea-breeze circulation. It also generates vertical profiles of mixing ratio that compare better to the observations than the uncoupled simulation and air potential temperature and wind vertical profiles that represent particular features of the atmospheric circulation at Cabo Frio.  相似文献   
93.
Among chemical industries, petroleum refineries have been identified as large emitters of a wide variety of pollutants. Benzene, toluene, ethylbenzene, and xylene (BTEX) form an important group of aromatic volatile organic compounds (VOCs) because of their role in the troposphere chemistry and the risk posed to human health. A very large crude oil refinery of the Baltic States (200,000 bbl/day) is situated in the northern, rural part of Lithuania, 10 km from the town of Ma?eikiai (Lithuania). The objectives of this study were: (1) to determine of atmospheric levels of BTEX in the region rural and urban parts at the vicinity of the crude oil refinery; and (2) to investigate the effect of meteorological parameters (wind speed, wind direction, temperature, pressure, humidity) on the concentrations measured. The averaged concentration of benzene varied from 2.12 ppbv in the rural areas to 2.75 ppbv in the urban areas where the traffic was determined to be a dominant source of BTEX emissions. Our study showed that concentration of benzene, as strictly regulated air pollutant by EU Directive 2008/50/EC, did not exceed the limit of 5 ppbv in the region in the vicinity of the crude oil refinery during the investigated period. No significant change in air quality in the vicinity of the oil refinery was discovered, however, an impact of the industry on the background air quality was detected. The T/B ratio (0.50-0.81) that was much lower than 2.0, identified other sources of pollution than traffic.  相似文献   
94.
95.
A new methodology for the assessment of thiocyanate (SCN(-)) is proposed based on optical fiber (OF) detection coupled to a liquid chromatography system (LC). The developed methodology showed an adequate performance for the analysis of SCN(-) comparable to a high performance liquid chromatography with UV detector (HPLC-UV) methodology: a detection limit of 3 μg L(-1), a linear range from 4 to 400 μg L(-1), and an analytical time of less than 6 min. The OF based methodology was of compact design and easy operation. This simple system has the potential to be used as a sensing approach for SCN(-) in seawater.  相似文献   
96.
DNA damage was evaluated in the haemolymph of Mytilus galloprovincialis from nine sites along the south coast of Portugal using the comet assay. DNA damage was low, in the same range of sites considered to suffer low impact from genotoxic contaminants. Even so, differences between sites, seasons and genders were found. Highest values were in mussels from the main estuaries and the fishery harbour, reflecting higher genotoxin levels, whereas the lowest values can be used as a baseline for future work. Non-contaminant related factors (e.g. temperature and oxygen) were also shown to influence DNA damage. Between seasons, highest values were in summer related not only to the increase of tourism in this region (~10-fold), but also to temperature. Between genders, males were found to be more sensitive. The condition index was also generally higher in summer. Lipid peroxidation, another damage biomarker, was measured in gills to assess if there is any association between the responses of both biomarkers and if they are similarly affected by the same environmental conditions. LPO like DNA damage was higher in summer. This work confirms that DNA damage is a sensitive biomarker to discriminate genotoxic contamination, even in areas considered to suffer low impact from genotoxins.  相似文献   
97.
Food and Environmental Virology - Norovirus is a major cause of foodborne-associated acute gastroenteritis (AGE) outbreaks worldwide. Usually, food products are contaminated either during...  相似文献   
98.
Food and Environmental Virology - Enteric viruses have been described as important contaminants in fresh and ready-to-eat foods such as sandwiches, deli meat and dairy products. This is a...  相似文献   
99.
Environmental Science and Pollution Research - In this work, graphene oxide (GO) was synthesized by the modified Hummers method. The nanomaterial was characterized by FTIR and Raman spectroscopy,...  相似文献   
100.
The objective is to describe and quantify the diel variability of water quality in a tropical coastal system, Guanabara Bay, Brazil. Water samples were collected in spring and neap tide cycles over 24 h periods at three strategic sites. A pollution gradient was evident between the sampling sites. The average fecal coliform values decreased from 106 (site 3, most polluted) to 101 (site 1, less polluted). Organic matter mineralization was found in a similar gradient to organic pollution. However, complete nitrification was only found associated to regions where the water quality was better. Variability in this data set was determined mostly by the pollution gradient observed, and by tidal influence as well. The poor water quality indicates that the bay undergoes severe environmental stress. However water renewal promoted by tidal action was an important mechanism in diluting the pollution, improving water quality even in ebb tides and in the inner channels. The significance of micro-scale changes in water quality assessment in Guanabara Bay was confirmed, as well as the importance of these strategic sampling sites, reinforcing the importance of these measurements in monitoring programs.  相似文献   
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